MEK(Methyl Ethyl Ketone)

Physical and chemical properties

Physical statecolourless liquid
ColourColorless liquid
OdourAcetone-like odor
Melting point/ freezing point-87 °C
Boiling point or initial boiling point and boiling range80°C(lit.)
FlammabilityClass IB Flammable Liquid: Fl.P. below 22.78°C and BP at or above 37.78°C.Highly flammable.
Lower and upper explosion limit / flammability limitLower flammable limit: 1.4% by volume @ 200 deg F (93°C); Upper flammable limit: 11.4% by volume @ 200 deg F (93°C)
Flash point-3°C
Auto-ignition temperature515.56°C
Decomposition temperatureno data available
pHno data available
Kinematic viscosity0.40 cP at 25°C
SolubilityIn water:290 g/L (20 oC)
Partition coefficient n-octanol/water (log value)log Kow = 0.29
Vapour pressure71 mm Hg ( 20 °C)
Density and/or relative density0.805g/mLat 25°C(lit.)
Relative vapour density2.49 (vs air)
Particle characteristicsno data available


Stability and reactivity

1.Reactivity

   no data available

2.Chemical stability

   Stability during transport: stable

3.Possibility of hazardous reactions

   Highly flammable liquid.The vapour is heavier than air and may travel along the ground; distant ignition possible.METHYL       ETHYL KETONE is explosive in the form of vapor when exposed to heat, flame or sparks. Ignition on contact with potassium     tert-butoxide. Reactive with strong oxidizing materials, and will dissolve or soften some plastics. Mixture with 2-propanol          will form explosive peroxides during storage. Vigorous reaction with chloroform in the presence of alkali (sodium                      hydroxide, potassium hydroxide), chlorosulfonic acid, fuming sulfuric acid (oleum) [Lewis, 3rd ed., 1993, p. 855]. Reaction          with hydrogen peroxide in the presence of nitric acid forms heat- and shock-sensitive explosive acetone peroxides.                   [Bjorklund, G. H. et al., Trans. R. Soc. Can, 1950, 44, p. 25].

4.Conditions to avoid

    no data available

5.Incompatible materials

   Reacts violently with strong oxidants and inorganic acids causing fire and explosion hazard. Attacks some plastic.

6.Hazardous decomposition products

   MEK in air is rapidly decomposed by photochemical processes, mainly through oxidation by hydroxyl free radicals as well as      some decomposition by direct photolysis ... /with a/ half-life of 5.4 hr for photochemical decomposition in urban                      atmospheres.



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